Nitrone-Mediated Radical Coupling of Polymers Derived from Reverse Iodine-Transfer Polymerization

Reverse Iodine Transfer Polymerization (RITP) of Chloroprene

Nitroxide-Mediated Radical Polymerization of Styrene Initiated from the Surface of Titanium Oxide Nanoparticles

Titanium dioxide (TiO2) nanoparticles, with an average size of about 45 nm, were encapsulated by polystyrene using in situ nitroxide mediated radical polymerization   in the presence of 3-aminopropyl triethoxy silane (APTES) as a coupling agent and 2, 2, 6, 6-tetramethylpiperidinyl-1-oxy  as a initiator. First, the initiator for NMRP was covalently bonded onto the surface of Titanium dioxide na...

Nitrone-mediated radical coupling reactions: a new synthetic tool exemplified on dendrimer synthesis.

A synthetic strategy employing nitrones as radical spin traps is presented on the example of the efficient generation of novel dendrimers via a combination of radical and classical 'click' chemistry.

Mathematical Modeling of Atom Transfer Radical Polymerization

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Filling polymersomes with polymers by peroxidase-catalyzed atom transfer radical polymerization.

Polymersomes that encapsulate a hydrophilic polymer are prepared by conducting biocatalytic atom transfer radical polymerization (ATRP) in these hollow nanostructures. To this end, ATRPase horseradish peroxidase (HRP) is encapsulated into vesicles self-assembled from poly(dimethylsiloxane)-block-poly(2-methyl-2-oxazoline) (PDMS-b-PMOXA) diblock copolymers. The vesicles are turned into nanoreact...